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catena-Poly[[(3-acetylpyridine)copper(I)]mu(3)-chloro]

Journal article
Authors Anders Lennartson
Kent Salo
Mikael Håkansson
Published in Acta Crystallographica Section E-Structure Reports Online
Volume 61
Pages M1261-M1263
Publication year 2005
Published at Department of Chemistry
Pages M1261-M1263
Language en
Links <Go to ISI>://000230167400008
Keywords CRYSTAL-STRUCTURES, COMPLEXES, PYRIDINE, ADDUCTS
Subject categories Chemical Sciences

Abstract

In the search for ketone complexes suitable for absolute asymmetric synthesis, that is, complexes crystallizing in Sohncke space groups, we have studied complexes between copper( I) halides and acetylpyridines. The structure of polymeric [CuCl(3-acpy)](n) (3-acpy is 3-acetylpyridine, C7H7NO), a compound which was found to form achiral chains crystallizing in a centrosymmetric space group, is reported here. The complex forms ladder-type chains, in which the Cu-I atom is coordinated by one N atom and three Cl atoms in a tetrahedral geometry. In the crystal structure, the chains are interconnected through C - H....Cl and C - H.....O intermolecular contacts.

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