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DECAY DYNAMICS IN MOLECUL… - University of Gothenburg, Sweden Till startsida
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Journal article
Authors Klavs Hansen
Published in Mass Spectrometry Reviews
ISSN 0277-7037
Publication year 2020
Published at Department of Physics (GU)
Language en
Subject categories Physical Sciences


The phenomenon of power law decays in molecular beams is reviewed. The transition from a canonical to a microcanonical description of the decay is analyzed, and the appearance of the power law decay derived. Deviations from a power law often contain information on parallel competing processes. This is illustrated with examples where thermal radiation or dark unimolecular channels are the competing processes. Also corrections to the power law due to finite heat capacities and from nonideal energy distributions are derived. Finally, the consequences for the interpretation of action spectroscopy data are reviewed. (c) 2020 The Authors. Mass Spectrometry Reviews published by Wiley Periodicals, Inc. Mass Spec Rev

Page Manager: Webmaster|Last update: 9/11/2012

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