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An iron(III) iodosylbenzene complex: A masked non-heme FeVO

Journal article
Authors Anders Lennartson
Christine J. McKenzie
Published in Angewandte Chemie - International Edition
Volume 51
Pages 6767-6770
ISSN 14337851
Publication year 2012
Published at
Pages 6767-6770
Language en
Keywords biomimetic synthesis, enzyme models, iodosylbenzene, iron, oxygen transfer
Subject categories Chemical Sciences

Abstract

Coordinative flexibility and ligand bifunctionality play important roles in a biomimetic iron complex of a hexadentate ligand (see picture). This system can bind an auxiliary iodosylbenzene ligand to give the first structurally characterized metal complex of this important oxidizing agent. The complex is a protected precursor for Fe V O species, and the selective high-yielding catalytic oxygenation of a sulfide is demonstrated. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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