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Absolute Asymmetric Synthesis of a Tetrahedral Silver Complex

Journal article
Authors Per Martin Björemark
Susanne Olsson
Theonitsa Kokoli
Mikael Håkansson
Published in Chemistry-a European Journal
Volume 21
Issue 24
Pages 8750-8753
ISSN 0947-6539
Publication year 2015
Published at Department of Chemistry and Molecular Biology
Pages 8750-8753
Language en
Links dx.doi.org/10.1002/chem.201500986
Keywords asymmetric synthesis, chirality, inorganic stereochemistry, metal complexes, Viedma ripening, ATTRITION-ENHANCED DERACEMIZATION, CHIRAL-SYMMETRY-BREAKING, SPONTANEOUS, RESOLUTION, GRIGNARD-REAGENTS, CRYSTALLIZATION, AUTOCATALYSIS, HOMOCHIRALITY, CONFIGURATION, MOLECULES, MECHANISM, Chemistry
Subject categories Chemical Sciences

Abstract

Even though the isolation of tetrahedral stereoisomers usually presents a synthetic challenge, a highly enantioenriched tetrahedral silver complex could be easily accessed by either crystallization or Viedma ripening. The overall preparation may be regarded as an example of absolute asymmetric synthesis. Experimental results indicate that both crystallization and Viedma ripening follow a similar cluster-controlled mechanism.

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