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A missing link between chiral four- and five-coordinate complexes

Magazine article
Authors Anders Lennartson
Mikael Håkansson
Published in New Journal of Chemistry
Volume 39
Issue 5
Pages 3353-3356
ISSN 1144-0546
Publication year 2015
Published at Department of Chemistry and Molecular Biology
Pages 3353-3356
Language en
Links dx.doi.org/10.1039/c5nj00265f
Keywords Absolute Asymmetric-Synthesis, Spontaneous Resolution, Optical, Resolution, Racemic Crystals, Crystallization
Subject categories Chemical Sciences

Abstract

We report total spontaneous resolution and absolute asymmetric synthesis of [Pd(hfacac)(2)P(o-tol)(3)] (hfacac = hexafluoroacetylacetonate, P(o-tol)(3) = tri(o-tolyl)phosphine), a chiral complex with a coordination geometry intermediate between square-planar, square pyramidal and trigonal bipyramidal.

Page Manager: Webmaster|Last update: 9/11/2012
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