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Solvent dependent reductive defluorination of aliphatic C-F bonds employing Sm(HMDS)(2)

Journal article
Authors Mario Janjetovic
Annika M. Träff
Tobias Ankner
Jenny Wettergren
Göran Hilmersson
Published in Chemical Communications
Volume 49
Issue 18
Pages 1826-1828
ISSN 1359-7345
Publication year 2013
Published at Department of Chemistry and Molecular Biology
Pages 1826-1828
Language en
Subject categories Chemical Sciences


Sm(HMDS)(2) in n-hexane mediates fast cleavage of primary, secondary and tertiary alkyl fluorides in good to excellent yields. In n-hexane Sm(HMDS)(2) exhibits uniquely enhanced reductive ability towards the C-F bond compared to when using THF as solvent.

Page Manager: Webmaster|Last update: 9/11/2012

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