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| Authors |
Martin Jarenmark Håkan Carlsson Vladimir M. Trukhan Matti Haukka Sophie E. Canton Monica Walchak Wilfred Fullagar Willy Sundström Ebbe Nordlander |
|---|---|
| Published in | Inorganic Chemistry Communications |
| Volume | 13 |
| Issue | 3 |
| Pages | 334-337 |
| ISSN | 1387-7003 |
| Publication year | 2010 |
| Published at | |
| Pages | 334-337 |
| Language | en |
| Keywords | unsymmetric, FeZn, model complexe, plant purple acid phosphatase |
| Subject categories | Bio-inorganic chemistry |
The heterodinuclear complexes [FeZn(L)(CH3CO2)2]+ (L = ICIMP or IPCPMP) are structural models for the dinuclear active sites of plant purple acid phosphatases. They can be systematically synthesized from mononuclear iron complexes and enhance the rate of transesterification of 2-hydroxypropyl p-nitrophenyl phosphate, an assay for the catalytic hydrolysis performed by purple acid phosphatases.
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