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Total spontaneous resolution of five-coordinate complexes.

Journal article
Authors Anders Lennartson
Mikael Håkansson
Published in Angewandte Chemie (International ed. in English)
Volume 48
Issue 32
Pages 5869-71
ISSN 1521-3773
Publication year 2009
Published at Department of Chemistry
Pages 5869-71
Language en
Keywords asymmetric synthesis • chiral resolution • circular dichroism • five-coordinate complexes • structure elucidation
Subject categories Chemical Sciences


Talking about a resolution: Bulk quantities of five-coordinate complexes have been resolved for the first time using zinc and cadmium diethyldithiocarbamate species. The stereochemical outcome can be controlled by seeding with the desired isomer, giving access to either enantiomer in high enantiomeric excess and yield.

Page Manager: Webmaster|Last update: 9/11/2012

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