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Non-stochastic homochiral helix crystallization: cryptochirality in control?

Journal article
Authors Marcus Vestergren
A. Johansson
Anders Lennartson
Mikael Håkansson
Published in Mendeleev Communications
Issue 6
Pages 258-260
Publication year 2004
Published at Department of Chemistry
Pages 258-260
Language en
Links <Go to ISI>://000226749500014
Keywords ABSOLUTE ASYMMETRIC-SYNTHESIS, CHIRAL-SYMMETRY-BREAKING, COORDINATION, POLYMERS, SOLID-STATE, AUTOCATALYSIS, COMPLEXES, AMPLIFICATION, CONFIGURATION, MOLECULES, CRYSTALS
Subject categories Chemical Sciences

Abstract

A non-random distribution of handedness among homochiral batches, comprising air-sensitive CuCl/triallylamine coordination helices, was obtained during total spontaneous resolution from neat triallylamine.

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