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Systematic synthesis of functional unsymmetric FeZn model complexes for plant purple acid phosphatases

Journal article
Authors Martin Jarenmark
Håkan Carlsson
Vladimir M. Trukhan
Matti Haukka
Sophie E. Canton
Monica Walchak
Wilfred Fullagar
Willy Sundström
Ebbe Nordlander
Published in Inorganic Chemistry Communications
Volume 13
Issue 3
Pages 334-337
ISSN 1387-7003
Publication year 2010
Published at
Pages 334-337
Language en
Keywords unsymmetric, FeZn, model complexe, plant purple acid phosphatase
Subject categories Bio-inorganic chemistry


The heterodinuclear complexes [FeZn(L)(CH3CO2)2]+ (L = ICIMP or IPCPMP) are structural models for the dinuclear active sites of plant purple acid phosphatases. They can be systematically synthesized from mononuclear iron complexes and enhance the rate of transesterification of 2-hydroxypropyl p-nitrophenyl phosphate, an assay for the catalytic hydrolysis performed by purple acid phosphatases.

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